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Originally posted by ibiubu
I can prove it through the experiments that i outlined to the above people. I'm not sure if it will go anywhere as it is beyond my control. Furthermore, my interest in this issue has more than faded.
Originally posted by jthomas
Originally posted by Jezus
No one has proved it is physically possible for the buildings to collapse like that without explosives or some other variable.
That is obviously enough of a reason to have another investigation.
That I take as a direct claim that NIST did not demonstrate the collapse mechanism.
To which I responded:
---
"NIST showed how. No one has yet refuted the NIST reports.
"And don't forget that no one has produced any positive evidence for explosives."
Originally posted by jthomas
"Remember, the burden of proof lies with those who want to convince some entity for the need for another investigation. I'm trying to get that across to bsbray11 and he doesn't yet understand that trying to shift the burden of proof for his claims to others will not get him a new investigation."
The severe corrosion and subsequent erosion of Samples 1 and 2 are a very unusual event. No clear explanation for the source of the sulfur has been identified. The rate of corrosion is also unknown. It is possible that this is the result of long-term heating in the ground following the collapse of the buildings. It is also possible that the phenomenon started prior to collapse and accelerated the weakening of the steel structure. A detailed study into the mechanisms of this phenomenon is needed to determine what risk, if any, is presented to existing steel structures exposed to severe and long-burning fires.
Discuss This Article ( Note - this link is outdated! ) :
( www.wpi.edu... )
The "Deep Mystery" of Melted Steel
There is no indication that any of the fires in the World Trade Center buildings were hot enough to melt the steel framework. Jonathan Barnett, professor of fire protection engineering, has repeatedly reminded the public that steel--which has a melting point of 2,800 degrees Fahrenheit--may weaken and bend, but does not melt during an ordinary office fire. Yet metallurgical studies on WTC steel brought back to WPI reveal that a novel phenomenon--called an eutectic reaction--occurred at the surface, causing intergranular melting capable of turning a solid steel girder into Swiss cheese.
Materials science professors Ronald R. Biederman and Richard D. Sisson Jr. confirmed the presence of eutectic formations by examining steel samples under optical and scanning electron microscopes. A preliminary report was published in JOM, the journal of the Minerals, Metals & Materials Society. A more detailed analysis comprises Appendix C of the FEMA report. The New York Times called these findings "perhaps the deepest mystery uncovered in the investigation." The significance of the work on a sample from Building 7 and a structural column from one of the twin towers becomes apparent only when one sees these heavy chunks of damaged metal.
An one-inch column has been reduced to half-inch thickness. Its edges--which are curled like a paper scroll--have been thinned to almost razor sharpness. Gaping holes--some larger than a silver dollar--let light shine through a formerly solid steel flange. This Swiss cheese appearance shocked all of the fire-wise professors, who expected to see distortion and bending--but not holes.
An eutectic compound is a mixture of two or more substances that melts at the lowest temperature of any mixture of its components. Blacksmiths took advantage of this property by welding over fires of sulfur-rich charcoal, which lowers the melting point of iron. In the World Trade Center fire, the presence of oxygen, sulfur and heat caused iron oxide and iron sulfide to form at the surface of structural steel members. This liquid slag corroded through intergranular channels into the body of the metal, causing severe erosion and a loss of structural integrity.
The important questions, says Biederman, are how much sulfur do you need, and where did it come from. The answer could be as simple--and this is scary- as acid rain.
Have environmental pollutants increased the potential for eutectic reactions? "We may have just the inherent conditions in the atmosphere so that a lot of water on a burning building will form sulfuric acid, hydrogen sulfide or hydroxides, and start the eutectic process as the steel heats up," Biederman says. He notes that the sulfur could also have come from contents of the burning buildings, such as rubber or plastics. Another possible culprit is ocean salts, such as sodium sulfate, which is known to catalyze sulfidation reactions on turbine blades of jet engines. "All of these things have to be explored," he says.
From a building-safety point of view, the critical question is: Did the eutectic mixture form before the buildings collapsed, or later, as the remains smoldered on the ground. "We have no idea," admits Sisson. "To answer that, we would need to recreate those fires in the FPE labs, and burn fresh steel of known composition for the right time period, with the right environment." He hopes to have the opportunity to collaborate on thermodynamically controlled studies, and to observe the effects of adding sulfur, copper and other elements. The most important lesson, Sisson and Biederman stress, is that fail-safe sprinkler systems are essential to prevent steel from reaching even 1,000 degrees Fahrenheit, because phase changes at the 1,300-degree mark compromise a structure's load-bearing capacity.
The FEMA report calls for further metallurgic investigations, and Barnett, Biederman and Sisson hope that WPI will obtain NIST funding and access to more samples. They are continuing their microscopic studies on the samples prepared by graduate student Jeremy Bernier and Marco Fontecchio, the 2001–02 Helen E. Stoddard Materials Science and Engineering Fellow. (Next year's Stoddard Fellow, Erin Sullivan, will take up this work as part of her graduate studies.) Publication of their results may clear up some mysteries that have confounded the scientific community.
-JKM
[email protected]
Maintained by: [email protected]
Last modified: Sep 02, 2004, 14:07 EDT
The problem isn't the capitalized "R" but the use of quotation marks. Any " or ' will prevent the color BB code from working.
This "will not work"
This 'will not work'
This will work
Thanks.
Gemwolf
ATS Staff
(Submitted August 25, 2006; in revised form September 7, 2006)
Microstructural examination of a beam from Building 7 showed that temperatures higher than 940°C were experienced in localized regions. Concurrent examination of the beam surfaces and surface layers showed evidence of extensive metal removal, and the analysis suggests that this removal occurred while the beam was exposed to the fire in the rubble pile after the building had collapsed.
to examine the microstructures of
the steels from the World Trade Center disaster to
determine the maximum exposure temperatures
and to identify the mechanism for the extensive
metal removal.
Page 17
(Submitted August 25, 2006; in revised form September 7, 2006)
Microstructural examination of a beam from Building 7 showed that temperatures higher than 940
°C were experienced in localized regions. Concurrent examination of the beam surfaces and surface
layers showed evidence of extensive metal removal, and the analysis suggests that this removal occurred
while the beam was exposed to the fire in the rubble pile after the building had collapsed.
Keywords: Building 7, microstructure, rubble pile, slag, sulfur, temperature
Introduction
The Worcester Polytechnic Institute Materials
Science and Engineering faculty was asked by the
Federal Emergency Management Agency (FEMA)
forensic team to examine the microstructures of
the steels from the World Trade Center disaster to
determine the maximum exposure temperatures
and to identify the mechanism for the extensive
metal removal. These determinations were based
on microstructural examination of portions of
a beam.
Steel beam samples from Building 7 were collected
during the FEMA forensic investigation
after the September 11, 2001, attack. The Building
7 sample was identified by its location. The samples
were collected by the FEMA forensic team from
the “pile of rubble” that had been burning for many
days. The samples had been exposed to the fires in
the building while it remained standing as well as
the fires in the rubble on the ground after the
building collapsed. In this sample beam, extensive
metal removal was observed with thickness decreases
up to ½ in. and very localized regions of total metal
loss. A photograph of the steel beam sample is
presented in Fig. 1.
Fig. 1 Severely eroded ½ in. wide flange beam from WTC 7.
Nominal composition (%) of the A36 steel plate is
0.29C max, 0.80-1.2Mn, 0.04P, 0.05S, 0.15-0.3Si,
bal Fe.
A photograph of a metallurgical
mount of a beam section is seen in Fig. 2.
Preliminary results from this investigation were
presented in 2001[1] and the FEMA report,[2] and
this case history updates those reports.
Fig. 2 Cross-sectional metallurgical mount.
Page 18
Microstructural Observations
Metallographic samples from
the beam were prepared from
several locations, including sections
with total metal loss and
thicker sections. The cross
sections were mounted and
polished using standard metallographic
practice.
Building 7 - A36 Steel
The microstructure of the steel
from Building 7 is typical of a
structural steel such as ASTM
A36. The wide flange beam displayed a microstructure
that consisted of a banded hot worked
mixture of ferrite and pearlite (Fig. 3). The
microstructures in these regions displayed no effects
of excessive heat or metal loss.
Fig. 3 Microstructure of unaffected A36 steel. White—ferrite; dark—banded pearlite. Pearlite
forms in bands due to manganese segregation and prior hot working. 4% nital etch.
In the regions of the beam that exhibited
extensive metal removal, an intergranular liquid slag
attack was observed (Fig. 4).
Fig. 4 Optical micrograph of near-surface region showing iron
oxide-iron sulfide eutectic structure, grain-boundary
attack, and decarburization.
Scanning electron
microscopy (SEM) with energy-dispersive X-ray
spectroscopy (EDS) identified the slag to be
comprised of Fe, O, and S (Fig. 5). Chemical
reactions including oxidation, sulfidation, and
decarburization occurred, as well as the usually
observed phase transformations in the steel.
As the temperature increases, several microstructural
changes[3] normally occur within the
steel. Two important intermediate temperature
transformation reactions that occur soften the steel.
These are the pearlite spheroidization reaction at
temperatures below the A1 temperature, and the
conversion from ferrite and pearlite to austenite at
temperatures above the A1 temperature and above
the A3 temperature, followed by transformation
back to pearlite and ferrite on cooling. Typical
examples of these transformations are presented in
Fig. 6 and 7, within the pearlite banded regions
near the bottom of Fig. 4. In Fig. 6, the Fe3C in
the pearlite had started to spheroidize. Also, some
pearlite bands have areas where a re-austenitization
had occurred and new finer-grained regions of
pearlite and ferrite formed on cooling (Fig. 7). These
observations indicate that the steel in this region
had experienced temperatures in the range of 550
to 850 °C.
An example of a typical near-surface microstructure
is shown in Fig. 8. This microstructure
shows the scale and slag reaction effects at the top
of the micrograph and the normal metallurgical
reactions that occurred in this steel on heating and
cooling toward the bottom. As the temperature
increased, some changes in the microstructure of
the steel occurred as a result of heating and cooling.
However, as higher temperatures occurred, microstructural
as well as chemistry changes occurred
due to the reactions with the environment. The
interaction of heat in a corrosive fire environment
resulted in exposing the steel to sulfidation, oxidation,
and reductions in thickness.
Page 19
Using EDS with SEM, it was determined that
the slag contained iron, oxygen, and sulfur (Fig.
5). The reaction of this slag with the steel resulted
in several metallurgical effects. First, the surface of
the steel was decarburized in this environment (Fig.
8). Second, the slag preferentially attacked the grain
(.......page 20 not available for free. Fig. 8 thus not seen yet.)
Fig. 5 Energy dispersive X-ray spectroscopy (EDS) analysis of eutectic region.(LT: this shows light-gray regions of FeS and FeO.)
Fig. 6 Typical microstructural changes that occur when A36
steel is heated to the vicinity of the eutectoid reaction
~727 °C (1340 °F), held for a short time, and cooled to
ambient (LT: room-) temperature. Arrow indicates partial carbide
spheroidization.
Fig. 7 Typical microstructural changes that occur when A36
steel is heated to above the eutectoid temperature ~727
°C (1340 °F) and cooled to ambient temperature. Arrow
indicates a typical region where conversion to an
austenite matrix (on heating) occurred followed by a
retransformation to a ferrite matrix on cooling.
Originally posted by Jezus
No alternative theory is necessary to prove a lack of evidence for another.
Evidence for explosives might help to theorize on a possible unknown variable, but fact is that it has not be proven to be physically possible for those building to collapse like that without explosives or some other unknown variable.
Technology Review - Published by MIT
Printer_friendly_article
January 21, 2005
Military Reloads with Nanotech
Smaller. Cheaper. Nastier. Those are the guiding principles behind the military's latest bombs. The secret ingredient: nanotechnology that makes for a bigger boom.
By John Gartner.
Nanotechnology is grabbing headlines for its potential in advancing the life sciences and computing research, but the Department of Defense (DoD) found another use: a new class of weaponry that uses energy-packed nanometals to create powerful, compact bombs.
With funding from the U.S. government, Sandia National Laboratories, the Los Alamos National Laboratory, and the Lawrence Livermore National Laboratory are researching how to manipulate the flow of energy within and between molecules, a field known as nanoenergentics, which enables building more lethal weapons such as "cave-buster bombs" that have several times the detonation force of conventional bombs such as the "daisy cutter" or MOAB (mother of all bombs).
Researchers can greatly increase the power of weapons by adding materials known as superthermites that combine nanometals such as nanoaluminum with metal oxides such as iron oxide, according to Steven Son, a project leader in the Explosives Science and Technology group at Los Alamos.
"The advantage (of using nanometals) is in how fast you can get their energy out," Son says.
Son says that the chemical reactions of superthermites are faster and therefore release greater amounts of energy more rapidly.
"Superthermites can increase the (chemical) reaction time by a thousand times," Son says, resulting in a very rapid reactive wave.
Son, who has been working on nanoenergetics for more than three years, says that scientists can engineer nanoaluminum powders with different particle sizes to vary the energy release rates. This enables the material to be used in many applications, including underwater explosive devices, primers for igniting firearms, and as fuel propellants for rockets.
However, researchers aren't permitted to discuss what practical military applications may come from this research.
Nanoaluminum is more chemically reactive because there are more atoms on the surface area than standard aluminum, according to Douglas Carpenter, the chief scientific officer at nanometals company Quantumsphere.
"Standard aluminum covers just one-tenth of one percent of the surface area (with atoms), versus fifty percent for nanoaluminum," Carpenter says.
Carpenter says the U.S. military has developed "cave-buster" bombs using nanoaluminum, and it is also working on missiles and torpedoes that move so quickly that they strike their targets before evasive actions can be taken.
"Nanoaluminum provides ultra high burn rates for propellants that are ten times higher than existing propellants," says Carpenter.
The military is also trying to make sure that its bullets kill quickly.
The U.S. Army Environmental Center began a program in 1997 to develop alternatives to the toxic lead that is used in the hundreds of millions of rounds that are annually fired during conflicts and at its training ranges. Carpenter says that although bullets using nanoaluminum are ready to be field tested, the government has been slow implement the technology.
"Getting the government to change the way they kill people is difficult," Carpenter says.
Because nanometal provides a higher concentration of energy while requiring fewer raw materials, the overall cost of these weapons would drop, according to Kevin Walter, vice president of technical business development at nanometals manufacturer Nanoscale Technologies.
"You get a little better bang for your buck," Walter says.
The nanometals can be produced in particles as small as eight nanometers, Walter says, and then combined with other chemicals to create the explosive materials, which can also be used for non-military applications including pyrotechnics and explosives for mining.
Nanotechnology "could completely change the face of weaponry," according to Andy Oppenheimer, a weapons expert with analyst firm and publisher Jane's Information Group. Oppenheimer says nations including the United States, Germany, and Russia are developing "mini-nuke" devices that use nanotechnology to create much smaller nuclear detonators.
Oppenheimer says the devices could fit inside a briefcase and would be powerful enough to destroy a building. Although the devices require nuclear materials, because of their small size "they blur the line with conventional weapons," Oppenheimer says.
The mini-nuke weapons are still in the research phase and may be surreptitiously funded since any form of nuclear proliferation is "politically contentious" because of the possibility that they could fall into the hands of terrorists, Oppenheimer says.
The creation of much smaller nuclear bombs adds new challenges to the effort to limit weapons of mass destruction, according to Oppenheimer.
"(The bombs) could blow open everything that is in place for arms control," Oppenheimer says. "Everything gets more dangerous."
Copyright Technology Review 2005.
Originally posted by TrickoftheShade
Originally posted by Jezus
No alternative theory is necessary to prove a lack of evidence for another.
Evidence for explosives might help to theorize on a possible unknown variable, but fact is that it has not be proven to be physically possible for those building to collapse like that without explosives or some other unknown variable.
This is a powerful argument for some sort of DEW as countenanced by Judy Wood. Or at least it is as powerful an argument for that as it is for the use of CD-style explosives, in that it relies purely on the weakness of the official report and continues with pure conjecture.
Remember, the burden of proof lies with those who want to convince some entity for the need for another investigation. I'm trying to get that across to bsbray11 and he doesn't yet understand that trying to shift the burden of proof for his claims to others will not get him a new investigation."