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Originally posted by Haroki
*** Ok, thanks for the heads up. Next time I go camping, and it's cold, I'll remember to not throw too much wood on the fire, cuz that'll disrupt the optimum air/fuel mixture and give me a cold fire. There's a message there, in case you missed it.***
Lean mixtures (fuel starved or oxygen starved) produce cooler combustion gases than does a stoichiometric mixture, primarily due to the excessive dilution by unconsumed oxygen and its associated nitrogen. Rich mixtures (too much fuel or oxygen) also produce cooler combustion gases than does a stoichiometric mixture, primarily due to the excessive amount of carbon which oxidises to form carbon monoxide, rather than carbon dioxide.
When all the fuel is combined with all the free oxygen, typically within a vehicle's combustion chamber, the mixture is chemically balanced and this AFR is called the stoichiometric mixture (often abbreviated to stoich)
The cross beams would be removed by the 200' plus core columns when they bent and broke off after their vertical load capacity was exceeded.
Originally posted by Griff
Originally posted by Haroki
Lean mixtures (fuel starved or oxygen starved) produce cooler combustion gases than does a stoichiometric mixture, primarily due to the excessive dilution by unconsumed oxygen and its associated nitrogen. Rich mixtures (too much fuel or oxygen) also produce cooler combustion gases than does a stoichiometric mixture, primarily due to the excessive amount of carbon which oxidises to form carbon monoxide, rather than carbon dioxide.
Bolding and parenthesis are mine.
BTW, for those that need the lesson. Stoichiometric when talking about fuel-to-air ratio means:
When all the fuel is combined with all the free oxygen, typically within a vehicle's combustion chamber, the mixture is chemically balanced and this AFR is called the stoichiometric mixture (often abbreviated to stoich)
There is no absolute rule of “black smoke = an oxygen-starved fire”. It’s not as simple as that. You need to consider the materials that are burning, for instance.
Large fires involving plastics produce copious quantities of black smoke..
www.hse.gov.uk...
Experienced fire investigator John J Lentini doesn’t appear to believe you can tell much from smoke colour:
While it is true that flammable liquids produce black smoke, so does any petroleum-based product. The color of the initial flame and smoke might have been important in the 1940s and 1950s when our furniture was made of cotton and wood, but most furniture today is made of nylon, polyester, and polyurethane. Even wood fires, deprived of oxygen, will produce black smoke. According to NFPA 921, Paragraph 3.6:
“Smoke color is not necessarily an indicator of what is burning. While wood smoke from a well ventilated or fuel controlled wood fire is light colored or gray, the same fuel under low-oxygen conditions, or ventilation-controlled conditions in a post-flashover fire can be quite dark or black. Black smoke can also be produced by the burning of other materials including most plastics or ignitable liquids.”
Light smoke may indicate that there are no petroleum products burning. Black smoke
indicates nothing meaningful.
www.atslab.com...
And as you can see from other photos, a simplistic “black smoke = oxygen starved” interpretation is a little simplistic.
Above is where my campfire lesson would have helped out you understand the fallacy of your argument.......
Any analysis that attempts to extract meaning from the smoke colour, then, should also consider what might be burning at that point in the WTC fire. What materials were available at that time, and what colour smoke would they be expected to produce? That kind of in-depth review might come up with something useful, but creating fictional rules based on the smoke colour certainly doesn’t.
Originally posted by Haroki
And as you can see from other photos, a simplistic “black smoke = oxygen starved” interpretation is a little simplistic.
Above is where my campfire lesson would have helped out you understand the fallacy of your argument.......
Any analysis that attempts to extract meaning from the smoke colour, then, should also consider what might be burning at that point in the WTC fire.
Originally posted by Griff
Originally posted by Haroki
And as you can see from other photos, a simplistic “black smoke = oxygen starved” interpretation is a little simplistic.
I've never said that black smoke equals oxygen starved.
What I've said is black smoke indicates a cooler fire than optimum.
What is so hard to understand that hydrocarbons produce black smoke because of the unburned carbon?
Unburned and acts as a heat sink.
Your photo says nothing of the oposite.
Why do you think fuel burns at optimium in an engine, but produces black smoke when burned in the outside air? Which is a hotter fire?
So, stop with the "black smoke=oxygen starved" strawman. That is NOT what we are saying.
Above is where my campfire lesson would have helped out you understand the fallacy of your argument.......
Your camp fire lesson doesn't say squat. Think of it this way.
You're in vaccum where you have limited oxygen. Throwing on more logs will not produce more heat as there is not enough oxygen to burn at optimum. An analysis of a campfire in open air (when talking about too much fuel) is a bad one. Sorry to say.
Any analysis that attempts to extract meaning from the smoke colour, then, should also consider what might be burning at that point in the WTC fire.
Yes, but one should also take into account the colour of the smoke throughout the entire fire.
It went from light to dark. I guess all the wood burned first and then the plastics later on?
Originally posted by Haroki
Your statement that black smoke means a less than optimum heat is misleading. A true statement would be is that burning materials that emit black smoke are less hot than materials that don't - for the exact reason you give, namely carbon. That object in my photo IS burning at optimum temperature for the materials that it's made from, correct? It's just that it may have a cooler flame temperature than other materials.
So when you attempt to debunk my campfire lesson, you still seem to be insinuating that there's limited oxygen.
or what is burning by looking at the smoke's color is by using direct observation of the flame color.
Originally posted by Haroki
Your statement that black smoke means a less than optimum heat is misleading. A true statement would be is that burning materials that emit black smoke are less hot than materials that don't - for the exact reason you give, namely carbon.
Originally posted by bsbray11
Originally posted by Haroki
The fact remains that the smoke coming out of the towers was mostly black and dark gray after the jet fuel burned up. Doesn't really matter why it was black, so long as we agree that it was fire and it was producing sooty smoke, right?
As far as office or skyscraper fires go, they were really minor.
We already understand that less-than-optimum fires put out less-than-optimum temperatures and heat. Optimum in this case would be about 825 C max. I would say we're more in the 600 - 700 C range generally with spots that may be hotter or cooler. There are things called flashovers too, that elevate temperatures briefly, but they don't last very long. And even NIST will tell you that the fires didn't stay where they were, but moved around a lot within the floors as they flared up and died down and were being fought. Imagine what that means, when you think all this steel all over the building was uniformly heated to some extreme temperature (all of the steel would be glowing dark red in broad daylight that was heated to 600 C), but the fires were sooty and roamed around and didn't even last longer than 2 hours in general.
You know all the steel in that building was certified as being able to withstand 2 hours of fire unprotected, right?
Yes there was sooty smoke, but as Griff agrees, that doen't mean that there was less than optimum burning. To say that is misleading. It's just that materials that produce black smoke may have cooler flame temps than a material that burns "clean". The only inference you can make is that when a material that normally burns "clean" is producing black smoke, it is burning at less than optimum temps. And since no one was there to testify what was burning, nothing can be gained by speculating on what materials were producing black smoke.
"Minor fires" sounds pretty subjective to me. And anyways, all of the examples you can give lack 2 things. 1- none were a "tube in tube" design - without concrete encasing their core columns, which aid immensely in a buildings ability to resist heat effects. 2- none had planes fly into them and sever many of their main load bearing columns. So anything you have is irrelevant to this case.
I'd say optimum temps would be 1000-1200C. And these flame colors (yellow-red) can be seen in some photos just before collapse. But most are in the 800-1000C range, granted. The point being, that the fires near the exterior exhibit these temps, which would lend credibility to the exterior columns buckling inward, as NIST states. Look at table 1.2 and judge for yourself.
www.tcforensic.com.au...
The WHOLE floor doesn't need to be heated uniformly at the same time. This a strawman, I believe. If it is supporting a vert load, and is heated to allow buckling, that would be enough, even if the fire moves on to another area later. You're the engineering student - so tell me, how much is a column's ability to support a vert load decreased after it's buckled? 1/2? Even you will agree that if enough load bearing capacity is removed, either by the plane or fire, the building WILL fall, correct? Even if other areas are totally unaffected. There IS a limit, correct?
The fires were being fought? Please tell me you were up late last night studying, and this is just a brain fart.
Certified for 2 hours? Please tell me you're not relying on Kevin Ryan's lies. Otherwise, you'll have to go on ignore. UL tested the trusses - with fireproofing- after 9/11 and certified that they preformed well, even though they did sag, which again, would lend credibility to the columns inward buckling.
Originally posted by Haroki
Yes there was sooty smoke, but as Griff agrees, that doen't mean that there was less than optimum burning.
"Minor fires" sounds pretty subjective to me.
1- none were a "tube in tube" design
I'd say optimum temps would be 1000-1200C.
Certified for 2 hours? Please tell me you're not relying on Kevin Ryan's lies.
Originally posted by bsbray11
Originally posted by Haroki
Certified for 2 hours? Please tell me you're not relying on Kevin Ryan's lies.
It's not lies, it's law. Griff? You've seen where NIST verified the steel was up to this code, right? If not, I'll have to post that later too. Bit of a hurry right now.
[edit on 20-11-2007 by bsbray11]
You stated that the trusses would able to survive 2 hours unprotected. Read the chart carefully. They all had fire proofing on them.
And here's a fav quote WHY the whole temp of the flames is irrelevant:
As is typical of folks who do not have a scientific background, the question is purely one of temperatures. But anyone with any knowledge of the science of combustion and melting knows that it is much more complicated than that.
If it were purely a matter of temperature, then as soon as the fire reached its maximum temperature, the steel would have melted, and the buildings would have collapsed -- all in a matter of seconds.
But it didn't take seconds, did it? It took nearly an hour before the first building fell. Why is that?
Because the problem isn't one of pure temperature, it is one of HEAT CAPACITY and THERMAL CONDUCTIVITY.
"Heat capacity (usually denoted by a capital C, often with subscripts) is a measurable physical quantity that characterizes the ability of a body to store heat as it changes in temperature. It is defined as the rate of change of temperature as heat is added to a body at the given conditions and state of the body (foremost its temperature). In the International System of Units, heat capacity is expressed in units of joules per kelvin. It is termed an "extensive quantity" because it is sensitive to the size of the object (for example, a bathtub of water has a greater heat capacity than a cup of water). Dividing heat capacity by the body's mass yields a specific heat capacity (also called more properly "mass-specific heat capacity" or more loosely "specific heat"), which is an "intensive quantity," meaning it is no longer dependent on amount of material, and is now more dependent on the type of material, as well as the physical conditions of heating." en.wikipedia.org...
"In physics, thermal conductivity, k, is the intensive property of a material that indicates its ability to conduct heat.
It is defined as the quantity of heat, Q, transmitted in time t through a thickness L, in a direction normal to a surface of area A, due to a temperature difference ΔT, under steady state conditions and when the heat transfer is dependent only on the temperature gradient.
Thermal conductivity = heat flow rate × distance / (area × temperature difference) "
en.wikipedia.org...
So, the poroblem here is not strictly one of temperature, but how much heat was being pumped into the steel, versus how quickly it could conduct that heat to other areas to cool itself down. If the steel conducts heat away from the fire faster than it is being pumped into the steel, the steel remains rigid. If heat is pumped into the steel faster than it can be conducted away, the temperature of the steel RISES ABOVE THE TEMPERATURE OF THE FIRE, eventually reaching the plastic deformation (softening) temperature. At that point, the steel girders deform, and the rest is purely momemtum (mass times velocity).
The world of ignore awaits you if you choose to continue....
[edit on 20-11-2007 by Haroki]
Originally posted by bsbray11
It's not lies, it's law. Griff? You've seen where NIST verified the steel was up to this code, right?
Originally posted by Haroki
You stated that the trusses would able to survive 2 hours unprotected. Read the chart carefully. They all had fire proofing on them.
As is typical of folks who do not have a scientific background
But anyone with any knowledge of the science of combustion
knows that it is much more complicated than that.
If it were purely a matter of temperature, then as soon as the fire reached its maximum temperature, the steel would have melted, and the buildings would have collapsed -- all in a matter of seconds.
Originally posted by bsbray11
Originally posted by Haroki
You stated that the trusses would able to survive 2 hours unprotected. Read the chart carefully. They all had fire proofing on them.
Then you want something that shows what happens without fireproofing, don't you?
As is typical of folks who do not have a scientific background
What's your background? Do you have a scientific background? What is your degree in and where did you get it?
Ever worked a free-body diagram? Ever analyzed any forces or momentums or anything like that as vectors in high school or college? What about materials science? Do you know the difference between a shear load and tensile and compressive loads? This stuff isn't even my field, and I'm going to have to say I know it better than you do. Even if you do somehow miraculously have a degree relevant to any of this, you don't show it in the least. You certainly never applied it. And least of all are you fooling anyone else that has had this stuff and has listening to other people drone on about these subjects for hours at a time.
But anyone with any knowledge of the science of combustion
Such as yourself, of course, since we just had to explain to you why sooty smoke indicates inefficient combustion. Not just once, but in several posts back to back, because you're hard-headed and just don't want to get it if it forces you to realize you're wrong.
knows that it is much more complicated than that.
Only if it fits your way of looking at things. Otherwise, it would be much simpler!
If it were purely a matter of temperature, then as soon as the fire reached its maximum temperature, the steel would have melted, and the buildings would have collapsed -- all in a matter of seconds.
Right. It depends on temperature AND heat. Unfortunately both were lacking. Do you want an explanation of what the difference is? Or do you want to prove NIST correct in assuming so many wood stoves' worth of heat was being produced per office area?
If you really knew what you were talking about (you're copying and pasting from Googling and I can tell), you would've noticed I was talking about heat transfer in earlier posts. Your slip usually show this often?
[edit on 20-11-2007 by bsbray11]
Originally posted by Haroki
Also noticed you never answered my Q about your claim that the fires were being fought. Just admit you had a weak moment dude......
Originally posted by bsbray11
Haroki, that last post was a complete rant and I'm still waiting for you to explain to all of us non-scientific types here what your degree is in and where you got it.
Originally posted by Haroki
Also noticed you never answered my Q about your claim that the fires were being fought. Just admit you had a weak moment dude......
I missed that comment but it really doesn't matter whether they were being fought or not. I know there were firemen in the building, I can only imagine what they would've been trying to do to the fires. Either way I can post a steel-framed structure laid out almost exactly like the towers (core structure and exterior columns carrying loads) that burned on the same range of floors for a longer period of time, completely gutting floors, and not losing any of its ability to hold itself up (First Interstate Bank), which was my point.
[edit on 21-11-2007 by bsbray11]
Originally posted by Haroki
1- whether or not the fires being fought matters cuz YOU claimed that they were as a way to explain how "cool" the fires were. So far, no evidence to show this.
2- You claimed that the unprotected steel was "certified" for 2 hrs. So far, no evidence to show this.
3- Griff agrees with me when I say that black smoke, etc is in no way a reliable way to determine fire temps.
I t is pure speculation on your part that the fires were burning at "less than optimum temps".
Griff also agrees that a better way of determining fire temps is to examine flame color. So far, no evidence from you to show that this is a better way to determine fire temps.
4- I would bet the farm that any buildings you have to show me DIDN'T have 767 hit them at 500+mph also.
NIST says that the buildings more than likely would have stood from fire alone or from the impacts alone,
Originally posted by Haroki
I t is pure speculation on your part that the fires were burning at "less than optimum temps".
Originally posted by ANOK
(BTW you guys seem to get all your de-bunking from 9-11myths huh?...)