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originally posted by: Degradation33
Once it passes a certain point, water can't exist. Pressure splits it apart.
We review mineral physics, geophysical, and geochemical studies related to the global water circulation and conclude that the water content has a peak in the mantle transition zone (MTZ) with a value of 0.1–1 wt% (with large regional variations). When water-rich MTZ materials are transported out of the MTZ, partial melting occurs. Vertical direction of melt migration is determined by the density contrast between the melts and coexisting minerals. Because a density change associated with a phase transformation occurs sharply for a solid but more gradually for a melt, melts formed above the phase transformation depth are generally heavier than solids, whereas melts formed below the transformation depth are lighter than solids. Consequently, hydrous melts formed either above or below the MTZ return to the MTZ, maintaining its high water content. However, the MTZ water content cannot increase without limit. The melt-solid density contrast above the 410 km depends on the temperature. In cooler regions, melting will occur only in the presence of very water-rich materials. Melts produced in these regions have high water content and hence can be buoyant above the 410 km, removing water from the MTZ.
Due to mantle convection and resultant partial melting and melt transfer, water may circulate deep into the mantle and return through Earth’s surface into the oceans.
Under the high temperature and pressure conditions deep in the Earth, silicate and fluids can be completely mixed, forging a supercritical geological fluid with the composition "thicker" than magmatic melts and "thinner" than aqueous liquids.
Fluids are like the "blood" inside the solid Earth, playing an important role in the transportation of matter and energy. Due to the compositional difference, rocks that are composed mainly of silicate and common fluids have a typically low level of miscibility.
This kind of melt network can facilitate the simultaneously capture of silicate melts and aqueous fluids with different proportions when mineral crystallizations crystalize. Meanwhile, the spinodal decomposition of the integral decomposition mechanism will significantly contribute to the efficiency of the melt-fluid phase separation, which may have important implications for the formation of magmatic hydrothermal deposits.
This study reported for the first time the spinodal decomposition of supercritical fluid and the formation of magmatic network.
originally posted by: Degradation33
But I'll give you the part about supercritical fluid in high pressure situations.
phys.org...
Under the high temperature and pressure conditions deep in the Earth, silicate and fluids can be completely mixed, forging a supercritical geological fluid with the composition "thicker" than magmatic melts and "thinner" than aqueous liquids.
And this is what the melt-aqueous binary supercritical fluids looks like:
Fluids are like the "blood" inside the solid Earth, playing an important role in the transportation of matter and energy. Due to the compositional difference, rocks that are composed mainly of silicate and common fluids have a typically low level of miscibility.
This study reported for the first time the spinodal decomposition of supercritical fluid and the formation of magmatic network.
I know you'll make this totally support that it is all floating in liquid water getting absorbed, because it yields that magic resevoir of water to flood Earth with.
originally posted by: Degradation33
a reply to: cooperton
Oh, blind preacher for the pineyed congregation, enlighten no one.
You can insert your own narrative where you want. But I'd stop short of thinking that you have earned right to explain this to anyone outside of a myopic religious environment.
I'm freaking annoyed by this. Little tolerance, making my skin crawl. Your obstinate true belief and alternate reality makes me want to scream.
Nevermind... switching up with this.
**********************
If your "reservoir" of "supercritical water", which is certainly not trapped inside crystaline structure, is exactly like you say, I want YOU to come up with a theory for how to transfer all the water in the MTZ to the surface in one day, or even 40 days, and remain in stable liquid form the entire time. THE ENTIRE FREAKING STORE OF WATER INSIDE MTZ CRYSTAL WITHOUT THE SILICATES
Another evangelical that does 'God's work' through making people hostile and wanting to hurt them.
This minute amount of water release from the mantle could be achieved by a slight expansion of the core, and/or an increased pressure or temperature in the mantle.
Under the high temperature and pressure conditions deep in the Earth, silicate and fluids can be completely mixed, forging a supercritical geological fluid with the composition "thicker" than magmatic melts and "thinner" than aqueous liquids.
Our results suggest that there is complete miscibility between silicate melts and water in most of the upper mantle,
You must interpret the above as meaning WATER IS ALMOST ALWAYS MIXED WITH SILICATE MELTS.
The supercritical geological fluid at this depth is a silicate-aqueous mix, you must acknowledge it's viscosity.
You must acknowledge "aqueous fluid" ≠ "supercritical fluid" in the MTZ.
originally posted by: Degradation33
Can you even acknowledge 95% of all H2O in the mantle is in the high-pressure olivine polymorph crystals? No? Didn't think so. Just gonna insert your own reality some more?
But still waiting to hear how you propose to change the pressure is earth enough to push all the 'water' out of the transition zone.
Turns out that the water was not trapped in the mineral, the mineral was dissolved in the water.
* Values match the thermodynamic database in VMINTEQ v. 3.1 except for italicized values, which are from MINEQL+ ver. 4.6. Underlined values are from Benjamin.1
Additional solids in the VMINTEQ database are not included here.
† Values are for the reaction MeX → Me + X, except for (hydr)oxide solids (i.e., Me(OH)x or MxOy, MeOOH) where the values are *Ks0 values (see section 10.5), and the
corresponding reactions are
Me(OH)x + xH+ → Mex+ + xH2O,
MexOy + 2yH+ → Me(2y/x)+ + yH2O,
MeOOH + 3H+ → Me3+ + 2H2O.
Other solids containing hydroxide release a hydroxide ion for the K values given.
§ Solubility constants for sulfide minerals assume pKa2 = 17.3 for HS– → H+ + S2–
, which is the value in VMINTEQ v. 3.1 and is consistent with recent measurements.2
You're referring to older out-dated sources. This source from 2023 says that there is actually very large amounts of water, they estimated around 40% of the weight of these deep subduction regions:
"Our research presents a method that more accurately determines the quantitative composition of ultrahigh-pressure (UHP) fluid [high H2O (~40 wt.%) and solute (~60 wt.%) contents] released by a slab during deep subduction compared with that detailed in previous studies. The data provide important information for understanding the characteristics of UHP fluids, especially supercritical fluids..."
This improves their recycling efficiency in the subduction zone, playing a vital role in the deep cycling of these elements. The contribution of supercritical fluids to the deep carbon and sulfur cycle may have been significantly underestimated previously.
inclusions in omphacite (Table 1). The SiO2 contents range from 12.9 wt.% to 31.5 wt.%, but typically fall around 25 wt.%, and the content of H2O is always around 45 wt.%
Omphacite is the dominated phase in the subducted oceanic crust in the Earth's upper mantle. The Mid-Ocean Ridge Basalt, which makes up oceanic crust, goes through ultrahigh-pressure metamorphic process and transforms to eclogite at depth ~60 km in the subduction zones.[9] The major mineral components of eclogite include omphacite, garnet and high-pressure silica phases (coesite and stishovite).[8] As depth increases, the omphacite in eclogite gradually transforms to majoritic garnet. Omphacite is stable up to 500 km depth in the Earth's interior.[8][10] Considering the cold geotherm of subducted slabs, omphacite can be stable even in deeper mantle..
Extensive infrared (IR) spectroscopic analyses on ‘nominally anhydrous minerals’ (NAMs), such as olivine, pyroxene and garnet, have revealed that they have a considerable ability to dissolve water and, hence, the upper mantle and the transition zone can be large reservoirs for water in Earthʼs interior (Bell and Rossman, 1992a, Hirschmann et al., 2005). (In this study, ‘water’ refers to any water-related species such as hydrogen, hydroxyl and/or molecular water detected as O–H stretching with infrared spectroscopy.) Garnets from ultrahigh-pressure metamorphic rocks have water contents up to ∼1000 wt. ppm H2O"
originally posted by: Phantom42338
a reply to: cooperton
Here's the solubility constants for most minerals and a link to the complete table. Did you calculate the concentration of each mineral to know how much was actually dissolved in water?
Here is a progression picture of water heating up (from right to left) to the point of becoming supercritical, and dissolving the remnants of the mineral melt:
originally posted by: Degradation33
a reply to: cooperton
FFS, YOU SOUND RETARDED.
Act like you understand that.
Such a pseudointellectual.
Do this on your level of understanding
If the supercritical fluid is a total mix of silicate/H20, how does it separate back into the pure water you need to flood the earth ?
I just skimmed through it, but I don't think this related to the water content of the transition zone
How does a "pressure change in the core" dehydrate the ringwoodite and wadsleyite" (and everything else) and send it all the way to the top of Mt. Everest, without releasing any magma or anything else ahead of it?
originally posted by: Degradation33
a reply to: cooperton
That was a hypothetical idiot question and you answered it seriously. I have to dumb myself down for this one.
So... the slab fluid, in supercritical form, in the upper mantle, above 200km, accompanying the subduction plate flooded the earth now?
So what does this have to do with the ringweoodite again?
That's where the most 'water' is.
You're the type of poster that makes people want to DOX them and show up to hurt them just for the fun if it. Just to feel better about the pseudointellectual creationist that pissed them off.
Why?
BECAUSE IT PISSES PEOPLE OFF WHEN A PSEUDOINTELLECTUAL CREATIONIST TELLS THEM THEY ARE WRONG USING FALLACY.
originally posted by: Degradation33
a reply to: Degradation33
NOW STOP SIDE STEPPING AND ANSWER THIS.
"How does a "pressure change in the core" dehydrate the ringwoodite and wadsleyite" (and everything else) and send it all the way to the top of Mt. Everest, without releasing any magma or anything else ahead of it?"